The technology for separation of zirconium and hafnium is the key to prepare nuclear grade productions of zirconium and hafnium. Zirconium and hafnium are normally associated together in nature (m(Hf)/m(Zr+Hf) is 1%−3%) and difficult to separate from each other. With the development of nuclear power, technologies for the separation between hafnium and zirconium, such as molten salt distillation , ion exchange and solvent extraction , have become very important because of the increasing demands for the production of nuclear grade hafnium and zirconium metals and compounds.